|
Glasses are solid materials without
crystalline molecular order. Unlike “traditional” solids, the atoms and
molecules in these materials are not packed in a regular grid-like pattern, but
are arranged in a more “random”, disordered fashion. Almost all materials can
be prepared in this form by cooling their melts at a fast enough rate. For
metal alloys, this requires cooling rates in excess of a million degrees per
second. For polymers, however, the required cooling rates are much slower, and
many polymers can be obtained in glassy form by simply letting their melts cool
in air. The same applies to common window glass, which is composed of silica with
certain impurities. Glasses are different from melts in
that they behave like solids when observed over short times (seconds or
minutes). At longer time scales (days, years), they show more and more liquid-like
behavior. Upon cooling a melt, the transition to glassy behavior does not occur
gradually, but quite sharply at a certain temperature, known as the glass
transition temperature. Many aspects of glasses and the glass transition are
still poorly understood, and represent an active field of current research.
|