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Members of Dr. Kasi’s Group Nominated for Best Poster at ACS Fall Meeting
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Ian J. Martin and Samiksha Vaidya of Dr. Rajeswari Kasi’s research group recently attended the American Chemical Society (ACS) Fall 2019 National Meeting & Exposition in San Diego, CA and presented posters entitled “Templated perylene diimide-polydiacetylene supramolecular structures with unique chromatic transitions” and “Molecular engineering of dye incorporated liquid-crystalline polymers with different architectures”, respectively. Each of their presentations were highlighted as distinguished poster nominees in the Polymeric Materials: Science and Engineering (PMSE) division.
Dr. Luyi Sun Elected as Member of CASE
Dr. Luyi Sun, Director of the IMS Polymer Program and Professor of Chemical and Biomolecular Engineering, was inducted into the academy at its 44th Annual Meeting in May 2019
Election to CASE is made on the basis of scientific and engineering distinction achieved through significant contributions in theory or applications, as demonstrated by original published books and papers, patents, the pioneering of new and developing fields and innovative products, outstanding leadership of nationally recognized technical teams, and external professional awards in recognition of scientific and engineering excellence.
Dr. Sun’s publication credits include such distinguished journals as Scientific Reports, Nature Communications, Science, and Science Advances, as well as holding several patents related to his research. His work has been featured in articles at Smithsonian.com, R&D Magazine, and Plastics Technology among other publications. Dr. Sun also serves as advisor to the UConn student chapter of the Society of Plastics Engineers (SPE).
IMS Director Dr. Steven L. Suib, also a CASE member elected in 2012, congratulated Dr. Sun on his membership and accomplishments at a celebration at IMS.
Intriguing Flexible Devices Based On Mechanoluminescence
Mechanoluminescence (ML), also called triboluminescence (TL), refers to the phenomenon/process that materials could emit light under mechanical stimuli, e.g., friction, stretch, compression, impact, etc. The ML materials could utilize the ubiquitous mechanical energy in daily life to generate light emissions, avoiding the requirement of an artificial photon- or electron-excitation source as that in photoluminescence (PL) or electroluminescence (EL). Therefore, ML materials show great advantages in energy saving and environmental protection.
For practical applications, ML crystals or powders are required to composite with bulk matrices to generate structural non-destructive ML. Among the fabricated ML composites, elastomer-based ones have attracted increasing attention owing to the rising requirement of incorporating stress sensing characteristic into flexible/wearable devices. The present ML elastomer composites mainly employ transition metal ion doped sulfides (TM-sulfides) as the luminescent components because of their intense ML intensity. However, the TM-sulfides usually have poor chemical stability and may cause severe environmental pollution as well as lack of rich emission color.
Theoretically, rare earth doped oxides (RE-oxides) are promising alternatives because of their high chemical stability, nontoxicity, and abundant energy levels. It is essential to develop efficient and ideally multicolored ML of RE-oxide based elastomer composites, so that flexible devices may possess remarkable and environmentally friendly mechanical responsive optical characteristics. Read the full story at Science Trends.
Polymer Program Seminar Series 2/9/2018
February 9, 2018
11.00am in IMS 20
Enhancing Enzymatic Activity with Nanoparticle Scaffolds – Towards Cell Free Biocatalysis
Igor L. Medintz
Center for Bio/Molecular Science and Engineering
U.S. Naval Research Laboratory
Washington D.C. U.S.A.
(Igor.medintz@nrl.navy.mil)
ABSTRACT
Enzymes and especially multienzyme pathways are of tremendous interest for the production of industrial chemicals and in the development of metabolic sensors. One primary focus of synthetic biology is to design enzymatic production capabilities in a “plug and play” format within cellular systems. Living cellular systems, however, can suffer from toxicity, competing pathways and sometimes an inability to mix enzymes from different species. Application of enzymes for industrial catalysis is often achieved by immobilization on a surface since this often provides stability and facilitates purification and reuse of the enzymes from the reaction mixture. Unfortunately, immobilization of enzymes on large planar surfaces often results in loss of enzymatic activity. We seek to create cell-free enzyme systems that can circumvent these issues in a “plug and play” format where enzymes are assembled on nanoparticle surfaces but still overcome diffusion and stability issues. We, and others, have demonstrated that immobilization of enzymes or substrate on nanoparticles often results in enhanced enzymatic activity relative to the free enzyme in solution. Mechanistic studies of this phenomena will be presented starting with substrate on nanoparticles and then progressing to the converse approach. Examples of multienzyme cascades assembled on nanoparticles that appear to access substrate channeling phenomena will also be presented. The challenges of characterizing and describing these complex organic/inorganic supramacromolecular systems will also be discussed in the context of further studies moving forward.
Host: Elena Dormidontova (elena@uconn.edu) and Mu-Ping Nieh (mu-ping.nieh@uconn.edu)